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Low Temp. Phys. 36, 1091 (2010); http://dx.doi.org/10.1063/1.3530423 (3 pages)

Kinetics of 4He gas sorption by fullerite C60. Quantum effects

A. V. Dolbin, V. B. Esel’son, V. G. Gavrilko, V. G. Manzhelii, N. A. Vinnikov, and S. N. Popov

B. Verkin Institute of Low Temperature Physics and Engineering, National Academy of Sciences of Ukraine, 47 Lenin Ave., Kharkov 61103, Ukraine

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The kinetics of helium gas sorption by C60 powder and subsequent desorption of the 4He impurity from the saturated powder is studied in the temperature interval 2–292 K. Evidence is obtained supporting the existence of two stages in the temperature dependences of sorption and desorption. These stages originate in different times taken by helium to occupy octahedral and tetrahedral interstices in the C60 lattice. The characteristic times of sorption and desorption coincide. It is found that the temperature dependences of the characteristic times for occupying the octahedral and tetrahedral interstices are nonmonotonic. When the temperature is lowered from 292 to 79.3 K, the characteristic times increase, which indicates thermally activated diffusion of helium in C60. With a further reduction to T = 10 K, the characteristic times decrease by more than an order of magnitude. Below 8 K the characteristic times of sorption and desorption are temperature-independent. This suggests tunnel diffusion of 4He in C60.

© 2010 American Institute of Physics

Article Outline

  1. INTRODUCTION
  2. EXPERIMENTAL TECHNIQUE
  3. RESULTS AND DISCUSSION
  4. CONCLUSIONS

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1063-777X (print)  
1090-6517 (online)

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    C. P. Chen, S. Mehta, L. P. Fu, A. Petrou, F. M. Gasparini, and A. Hebard, Phys. Rev. Lett. 71, 739 (1993).


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