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Low Temp. Phys. 34, 470 (2008); http://dx.doi.org/10.1063/1.2920178 (6 pages)

The effect of the noncentral impurity–matrix interaction upon the thermal expansion and polyamorphism of CO–C60 solid solutions at low temperatures

A. V. Dolbin1, V. B. Esel’son1, V. G. Gavrilko1, V. G. Manzhelii1, N. A. Vinnikov1, G. E. Gadd2, S. Moricca2, D. Cassidy2, and B. Sundqvist3

1B. Verkin Institute for Low Temperature Physics and Engineering of the National Academy of Sciences of Ukraine, 47 Lenin Ave., Kharkov 61103, Ukraine
2Australian Nuclear Science and Technology Organization, NSW 2234, Australia
3Department of Physics, Umea University, SE-901 87 Umea, Sweden

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Orientational glasses with CO molecules occupying 26 and 90% of the octahedral interstitial sites in the C60 lattice have been investigated by the dilatometric method in a temperature interval of 2.5–22 K. At temperatures of 4–6 K the glasses undergo a first-order phase transition which is evident from the hysteresis of the thermal expansion and the maxima in the temperature dependences of the linear thermal expansion coefficients α(T) and the thermalization times τ1(T) of the samples. The effect of the noncentral CO–C60 interaction upon the thermal expansion and the phase transition in these glasses was clarified by comparing the behavior of the properties of the CO–C60 and N2C60 solutions.

© 2008 American Institute of Physics

Article Outline

  1. INTRODUCTION
  2. SAMPLES AND MEASURING TECHNIQUE
  3. RESULTS AND DISCUSSION
  4. CONCLUSIONS

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KEYWORDS and PACS

PACS

  • 65.60.+a

    Thermal properties of amorphous solids and glasses: heat capacity, thermal expansion, etc.

  • 61.43.Fs

    Glasses

  • 64.70.ph

    Nonmetallic glasses (silicates, oxides, selenides, etc.)

ARTICLE DATA

PUBLICATION DATA

ISSN

1063-777X (print)  
1090-6517 (online)

For access to fully linked references, you need to log in.
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    I. Holleman, G. von Helden, A. van der Avoird, and G. Meijer, Phys. Rev. Lett. 80, 4899 (1998).


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